HRID92995

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID813

Potassium cation

K+

HCID8028

Tetrahydrofuran

C4H8O

HCID8857

Ethyl acetate

C4H8O2

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID3280088

未命名化合物

HCID11074324

Methyl 4-formylbicyclo[2.2.2]octane-1-carboxylate

C11H16O3

PRODUCTS

生成物

HCID22591686

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b50ec986cb1348a2a236c8652dba9dd9
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (2/10)

反应 SMILES

[Br-:25].[CH2:46]1[O:47][CH2:48][CH2:49][CH2:50]1.[CH3:1][Si:2]([CH3:3])([CH3:4])[N-:5][Si:6]([CH3:7])([CH3:8])[CH3:9].[CH3:26][P+:27]([c:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1)([c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1)[c:40]1[cH:41][cH:42][cH:43][cH:44][cH:45]1.[CH3:51][CH2:52][O:53][C:54]([CH3:55])=[O:56].[CH:11](=[O:12])[C:13]12[CH2:14][CH2:15][C:16]([C:21](=[O:22])[O:23][CH3:24])([CH2:17][CH2:18]1)[CH2:19][CH2:20]2.[K+:10]>>[CH2:1]=[CH:11][C:13]12[CH2:14][CH2:15][C:16]([C:21](=[O:22])[O:23][CH3:24])([CH2:17][CH2:18]1)[CH2:19][CH2:20]2