Salicylic Acid → 3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

HRID 934209Notes

Reaction equation

HRID 934209 reaction equation
[Al:31].[C:15]([CH3:17])([CH3:18])([O:19][OH:16])[CH3:20].[C:1]([CH3:2])(=[O:3])[O:4][CH2:5][CH:6]=[C:7]([CH3:8])[CH2:9][CH2:10][CH:11]=[C:12]([CH3:13])[CH3:14].[CH3:32][c:33]1[cH:34][cH:35][cH:36][cH:37][cH:38]1.[Cl:39][CH2:40][Cl:41].[O:42]=[Mn:43]=[O:44].[OH:21][C:22]([c:23]1[c:24]([OH:25])[cH:26][cH:27][cH:28][cH:29]1)=[O:30]>>[C:1]([CH3:2])(=[O:3])[O:4][CH2:5][CH:6]=[C:7]([CH3:8])[CH2:9][CH2:10][CH:11]=[C:12]([CH:13]=[O:19])[CH3:14]

Participants

8

Reactant 7

HCID 338Salicylic AcidHCID 1140TolueneHCID 6344DichloromethaneHCID 6410tert-Butyl hydroperoxideHCID 77803,7-Dimethylocta-2,6-dienyl acetateHCID 14801Manganese dioxideHCID 5359268Aluminum

Product 1

HCID 566095533,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Sources & evidence

ORD record
ord-5ecdfd5dbfd647d7b8ff58b90caba615
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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