Water → Ethyl 4-chloro-5-formyl-6,7-dihydro-3-methylthiobenzo[c]thiophene-1-carboxylate

HRID 937875Notes

Reaction equation

HRID 937875 reaction equation
[CH3:1][S:2][c:3]1[c:4]2[c:5]([c:6]([C:8](=[O:9])[O:10][CH2:11][CH3:12])[s:7]1)[CH2:13][CH2:14][CH2:15][C:16]2=[O:17].[CH3:28][N:29]([CH3:30])[CH:31]=[O:32].[CH:24]([Cl:25])([Cl:26])[Cl:27].[OH2:23].[P:18]([Cl:19])([Cl:20])([Cl:21])=[O:22]>>[CH3:1][S:2][c:3]1[c:4]2[c:5]([c:6]([C:8](=[O:9])[O:10][CH2:11][CH3:12])[s:7]1)[CH2:13][CH2:14][C:15]([CH:16]=[O:17])=[C:24]2[Cl:27]

Participants

6

Reactant 5

HCID 962WaterHCID 6212ChloroformHCID 6228DimethylformamideHCID 24813Phosphorus oxychlorideHCID 2778748Ethyl 3-(methylthio)-4-oxo-4,5,6,7-tetrahydrobenzo[c]thiophene-1-carboxylate

Product 1

HCID 2778781Ethyl 4-chloro-5-formyl-6,7-dihydro-3-methylthiobenzo[c]thiophene-1-carboxylate

Sources & evidence

ORD record
ord-1e3d00bc0a6543b7a2d3178f126b76ee
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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