Sodium ion → 4-(Chloromethyl)-2-nitroanisole

HRID 940163Notes

Reaction equation

HRID 940163 reaction equation
[CH3:1][O:2][c:3]1[c:4]([N+:11](=[O:12])[O-:13])[cH:5][c:6]([CH2:7][OH:8])[cH:9][cH:10]1.[Cl:33][N:34]1[C:35](=[O:36])[CH2:37][CH2:38][C:39]1=[O:40].[Cl:47][CH2:48][Cl:49].[Na+:41].[Na+:42].[O-:43][C:44](=[O:45])[O-:46].[c:14]1([P:15]([c:16]2[cH:17][cH:18][cH:19][cH:20][cH:21]2)[c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[cH:28][cH:29][cH:30][cH:31][cH:32]1>>[CH3:1][O:2][c:3]1[c:4]([N+:11](=[O:12])[O-:13])[cH:5][c:6]([CH2:7][Cl:33])[cH:9][cH:10]1

Participants

7

Reactant 6

HCID 923Sodium ion2×HCID 6344DichloromethaneHCID 11776TriphenylphosphineHCID 19660Carbonate IonHCID 31398ChlorosuccinimideHCID 4432413(4-Methoxy-3-nitrophenyl)methanol

Product 1

HCID 807854-(Chloromethyl)-2-nitroanisole

Sources & evidence

ORD record
ord-33a9610bd2134baf835d3bc37aee7af8
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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