Chloride → 2-{[5-(4-Chlorophenyl)pent-4-en-1-yl]oxy}oxane

HRID 940949Notes

Reaction equation

HRID 940949 reaction equation
[Cl-:6].[Cl:7][c:8]1[cH:9][cH:10][c:11]([CH2:12][P+:13]([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:32][cH:33]1.[Li:1][CH2:2][CH2:3][CH2:4][CH3:5].[O:34]1[CH:35]([O:40][CH2:41][CH2:42][CH2:43][CH:44]=[O:45])[CH2:36][CH2:37][CH2:38][CH2:39]1.[O:46]1[CH2:47][CH2:48][CH2:49][CH2:50]1>>[Cl:7][c:8]1[cH:9][cH:10][c:11]([CH:12]=[CH:44][CH2:43][CH2:42][CH2:41][O:40][CH:35]2[O:34][CH2:39][CH2:38][CH2:37][CH2:36]2)[cH:32][cH:33]1

Participants

6

Reactant 5

HCID 312ChlorideHCID 8028TetrahydrofuranHCID 551206Butanal, 4-[(tetrahydro-2H-pyran-2-yl)oxy]-HCID 2733547(4-Chlorophenyl)methyl-triphenylphosphaniumHCID 178418339Butyllithium

Product 1

HCID 544213722-{[5-(4-Chlorophenyl)pent-4-en-1-yl]oxy}oxane

Sources & evidence

ORD record
ord-4f670aad87ad40e4b4316ef090a8f52e
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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