Potassium Cation → Diethyl cyclopropane-1,1-dicarboxylate

HRID 940990Notes

Reaction equation

HRID 940990 reaction equation
[Br:18][CH2:19][CH2:20][Br:21].[C:12](=[O:13])([O-:14])[O-:15].[C:1]([CH2:2][C:3](=[O:4])[O:5][CH2:6][CH3:7])(=[O:8])[O:9][CH2:10][CH3:11].[CH2:28]([N+:29]([CH2:30][CH2:31][CH2:32][CH3:33])([CH2:34][CH2:35][CH2:36][CH3:37])[CH2:38][CH2:39][CH2:40][CH3:41])[CH2:42][CH2:43][CH3:44].[I-:27].[K+:16].[K+:17].[O:22]=[CH:23][N:24]([CH3:25])[CH3:26]>>[C:1]([C:2]1([C:3](=[O:4])[O:5][CH2:6][CH3:7])[CH2:19][CH2:20]1)(=[O:8])[O:9][CH2:10][CH3:11]

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 7761Diethyl MalonateHCID 78391,2-DibromoethaneHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 30165Iodide Ion

Product 1

HCID 73790Diethyl cyclopropane-1,1-dicarboxylate

Sources & evidence

ORD record
ord-7c9bfb4d37d64563be0ede95eaeb76bb
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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