Diisopropylamine → Aziridine, 2-(1,3-benzodioxol-5-yl)-

HRID 941786Notes

Reaction equation

HRID 941786 reaction equation
[Al+3:15].[CH:20]([NH:21][CH:22]([CH3:23])[CH3:24])([CH3:25])[CH3:26].[H-:14].[H-:17].[H-:18].[H-:19].[Li+:16].[O:1]1[CH2:2][O:3][c:4]2[c:5]1[cH:6][cH:7][c:8]([C:10]([CH3:11])=[N:12][OH:13])[cH:9]2.[O:27]1[CH2:28][CH2:29][CH2:30][CH2:31]1>>[O:1]1[CH2:2][O:3][c:4]2[c:5]1[cH:6][cH:7][c:8]([CH:10]1[CH2:11][NH:12]1)[cH:9]2

Participants

7

Reactant 6

HCID 7912DiisopropylamineHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 4661893Ethanone, 1-(1,3-benzodioxol-5-yl)-, oxime

Product 1

HCID 12316717Aziridine, 2-(1,3-benzodioxol-5-yl)-

Sources & evidence

ORD record
ord-25d42fdb3640496b824cb8e026a5d474
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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