Sodium ion → 9,10-Dihydro-4H-furo[2,3-e]pyrrolo[1,2-a][1,4]diazepine

HRID 942302Notes

Reaction equation

HRID 942302 reaction equation
[Al+3:2].[H-:1].[H-:4].[H-:5].[H-:6].[Li+:3].[Na+:23].[O:24]1[CH2:25][CH2:26][CH2:27][CH2:28]1.[OH-:22].[OH2:21].[o:7]1[cH:8][cH:9][c:10]2[c:11]1[NH:12][C:13](=[O:20])[c:14]1[n:15]([cH:17][cH:18][cH:19]1)[CH2:16]2>>[o:7]1[cH:8][cH:9][c:10]2[c:11]1[NH:12][CH2:13][c:14]1[n:15]([cH:17][cH:18][cH:19]1)[CH2:16]2

Participants

9

Reactant 8

HCID 923Sodium ionHCID 961HydroxideHCID 962WaterHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 100133324,10-dihydro-9H-furo[2,3-e]pyrrolo[1,2-a][1,4]diazepin-9-one

Product 1

HCID 218369669,10-Dihydro-4H-furo[2,3-e]pyrrolo[1,2-a][1,4]diazepine

Sources & evidence

ORD record
ord-9f29f4e10cb4421cbbb4eb392fef27ee
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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