Chloride → N'-[2-[(2-Chloro-3-pyridinylimino)phenylmethyl]phenyl]-N,N-dimethyl-1,3-propanediamine

HRID 942785Notes

Reaction equation

HRID 942785 reaction equation
[CH2:43]([Cl:44])[Cl:45].[CH3:1][N:2]([CH2:3][CH2:4][CH2:5][NH:6][c:7]1[c:8]([C:13](=[O:14])[c:15]2[cH:16][cH:17][cH:18][cH:19][cH:20]2)[cH:9][cH:10][cH:11][cH:12]1)[CH3:21].[CH3:30][CH2:31][N:32]([CH2:33][CH3:34])[CH2:35][CH3:36].[Cl-:46].[Cl-:47].[Cl-:48].[Cl-:49].[NH2:22][c:23]1[c:24]([Cl:29])[n:25][cH:26][cH:27][cH:28]1.[Ti+4:50].[cH:37]1[cH:38][cH:39][n:40][cH:41][cH:42]1>>[CH3:1][N:2]([CH2:3][CH2:4][CH2:5][NH:6][c:7]1[c:8]([C:13]([c:15]2[cH:16][cH:17][cH:18][cH:19][cH:20]2)=[N:22][c:23]2[c:24]([Cl:29])[n:25][cH:26][cH:27][cH:28]2)[cH:9][cH:10][cH:11][cH:12]1)[CH3:21]

Participants

8

Reactant 7

HCID 312Chloride4×HCID 1049PyridineHCID 6344DichloromethaneHCID 8471TriethylamineHCID 805282-Chloro-3-pyridylamineHCID 114942Titanium cation (4+)HCID 13604071[2-[[3-(Dimethylamino)propyl]amino]phenyl]phenylmethanone

Product 1

HCID 13749940N'-[2-[(2-Chloro-3-pyridinylimino)phenylmethyl]phenyl]-N,N-dimethyl-1,3-propanediamine

Sources & evidence

ORD record
ord-7828a1667f54421bbdb8a29408abfdd4
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…