Bicarbonate Ion → 2-[2-Bromo-3-(4-methoxy-benzyloxy)-benzyloxy]-tetrahydro-pyran

HRID 94388Notes

Reaction equation

HRID 94388 reaction equation
[Br:22][c:23]1[c:24]([CH2:39][OH:40])[cH:25][cH:26][cH:27][c:28]1[O:29][CH2:30][c:31]1[cH:32][cH:33][c:34]([O:37][CH3:38])[cH:35][cH:36]1.[CH2:1]1[CH2:2][O:3][CH:4]=[CH:5][CH2:6]1.[Cl:46][CH2:47][Cl:48].[Na+:45].[O-:41][C:42]([OH:43])=[O:44].[O:7]=[S:8](=[O:9])([OH:10])[CH2:11][C:12]12[CH2:13][CH2:14][CH:15]([C:16]1([CH3:17])[CH3:18])[CH2:19][C:20]2=[O:21]>>[CH2:1]1[CH2:2][O:3][CH:4]([O:40][CH2:39][c:24]2[c:23]([Br:22])[c:28]([O:29][CH2:30][c:31]3[cH:32][cH:33][c:34]([O:37][CH3:38])[cH:35][cH:36]3)[cH:27][cH:26][cH:25]2)[CH2:5][CH2:6]1

Participants

7

Reactant 6

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 6344DichloromethaneHCID 80803,4-dihydro-2H-pyranHCID 18462Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-HCID 59515252[2-Bromo-3-(4-methoxy-benzyloxy)-phenyl]-methanol

Product 1

HCID 595152152-[2-Bromo-3-(4-methoxy-benzyloxy)-benzyloxy]-tetrahydro-pyran

Sources & evidence

ORD record
ord-87b388f3ac014104b835be14f542c91d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

Loading…