HRID946247

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID23938

Palladium

HCID75806

Phosphine, tricyclohexyl-

C18H33P

HCID95417

1,5-Diphenyl-1,4-pentadien-3-one

C17H14O

HCID5462222

Potassium

结构：CC(C)[Si](S[Si](C(C)C)(C(C)C)C(C)C)(C(C)C)C(C)C

HCID11163810

未命名化合物

HCID20637256

未命名化合物

PRODUCTS

生成物

结构：CC(C)[Si](Sc1ccc2c3c([nH]c2c1)CCC3)(C(C)C)C(C)C

HCID20637253

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a4cab741fb69489da3b1c5185353dd60
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br:20][c:21]1[cH:22][cH:23][c:24]2[c:25]3[c:26]([nH:27][c:28]2[cH:29]1)[CH2:30][CH2:31][CH2:32]3.[CH:1]1([P:2]([CH:3]2[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]2)[CH:9]2[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]2)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1.[CH:33]([CH3:34])([CH3:35])[Si:36]([CH:37]([CH3:38])[CH3:39])([CH:40]([CH3:41])[CH3:42])[S:43][Si:44]([CH:45]([CH3:46])[CH3:47])([CH:48]([CH3:49])[CH3:50])[CH:51]([CH3:52])[CH3:53].[CH:60](=[CH:61][C:62]([CH:63]=[CH:64][c:65]1[cH:66][cH:67][cH:68][cH:69][cH:70]1)=[O:71])[c:72]1[cH:73][cH:74][cH:75][cH:76][cH:77]1.[K:54].[O:55]1[CH2:56][CH2:57][CH2:58][CH2:59]1.[Pd:78]>>[c:21]1([S:43][Si:36]([CH:33]([CH3:34])[CH3:35])([CH:37]([CH3:38])[CH3:39])[CH:40]([CH3:41])[CH3:42])[cH:22][cH:23][c:24]2[c:25]3[c:26]([nH:27][c:28]2[cH:29]1)[CH2:30][CH2:31][CH2:32]3