Tetrahydrofuran → 1,2,3,4-Tetrahydro-6-(triisopropylsilyl)thio cyclopent[b]indole

HRID 946247Notes

Reaction equation

[Br:20][c:21]1[cH:22][cH:23][c:24]2[c:25]3[c:26]([nH:27][c:28]2[cH:29]1)[CH2:30][CH2:31][CH2:32]3.[CH:1]1([P:2]([CH:3]2[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]2)[CH:9]2[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]2)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1.[CH:33]([CH3:34])([CH3:35])[Si:36]([CH:37]([CH3:38])[CH3:39])([CH:40]([CH3:41])[CH3:42])[S:43][Si:44]([CH:45]([CH3:46])[CH3:47])([CH:48]([CH3:49])[CH3:50])[CH:51]([CH3:52])[CH3:53].[CH:60](=[CH:61][C:62]([CH:63]=[CH:64][c:65]1[cH:66][cH:67][cH:68][cH:69][cH:70]1)=[O:71])[c:72]1[cH:73][cH:74][cH:75][cH:76][cH:77]1.[K:54].[O:55]1[CH2:56][CH2:57][CH2:58][CH2:59]1.[Pd:78]>>[c:21]1([S:43][Si:36]([CH:33]([CH3:34])[CH3:35])([CH:37]([CH3:38])[CH3:39])[CH:40]([CH3:41])[CH3:42])[cH:22][cH:23][c:24]2[c:25]3[c:26]([nH:27][c:28]2[cH:29]1)[CH2:30][CH2:31][CH2:32]3