HRID948882

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID923

Sodium ion

Na+

HCID6228

N,N-Dimethylformamide

C3H7NO

HCID7498

alpha-Bromotoluene

C7H7Br

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID16028

Tetrabutylammonium

C16H36N+

HCID30165

Iodide ion

I-

HCID166653

Hydride

H-

HCID54675757

Triacetic acid lactone

C6H6O3

PRODUCTS

生成物

HCID2784449

4-Benzyloxy-6-methyl-2H-pyran-2-one

C13H12O3

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-eb443537c3ab44a184691e664aa1a4db
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br:17][CH2:18][c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1.[CH2:31]([N+:32]([CH2:33][CH2:34][CH2:35][CH3:36])([CH2:37][CH2:38][CH2:39][CH3:40])[CH2:41][CH2:42][CH2:43][CH3:44])[CH2:45][CH2:46][CH3:47].[CH3:48][N:49]([CH3:50])[P:51]([N:52]([CH3:53])[CH3:54])([N:55]([CH3:56])[CH3:57])=[O:58].[H-:1].[I-:30].[Na+:2].[O:12]=[CH:13][N:14]([CH3:15])[CH3:16].[O:25]1[CH2:26][CH2:27][CH2:28][CH2:29]1.[OH:3][c:4]1[cH:5][c:6](=[O:11])[o:7][c:8]([CH3:10])[cH:9]1>>[O:3]([c:4]1[cH:5][c:6](=[O:11])[o:7][c:8]([CH3:10])[cH:9]1)[CH2:18][c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1