Sodium ion → 4,4-Dimethyl-1,2,3,4-tetrahydroquinoline

HRID 949766Notes

Reaction equation

HRID 949766 reaction equation
[Al+3:15].[CH2:23]1[O:24][CH2:25][CH2:26][CH2:27]1.[CH3:1][C:2]1([CH3:13])[CH2:3][C:4](=[O:12])[NH:5][c:6]2[cH:7][cH:8][cH:9][cH:10][c:11]21.[H-:14].[H-:17].[H-:18].[H-:19].[Li+:16].[Na+:22].[OH-:21].[OH2:20]>>[CH3:1][C:2]1([CH3:13])[CH2:3][CH2:4][NH:5][c:6]2[cH:7][cH:8][cH:9][cH:10][c:11]21

Participants

9

Reactant 8

HCID 923Sodium ionHCID 961HydroxideHCID 962WaterHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 142099454,4-Dimethyl-3,4-dihydroquinolin-2(1H)-one

Product 1

HCID 132194414,4-Dimethyl-1,2,3,4-tetrahydroquinoline

Sources & evidence

ORD record
ord-25118d4c6cac4f20abb822eaf22bdb00
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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