Potassium Cation → Ethyl 5-(2-pyridyl)-4-pentenoate

HRID 949873Notes

Reaction equation

HRID 949873 reaction equation
[C:36](=[O:37])([O-:38])[O-:39].[CH2:48]1[O:49][CH2:50][CH2:51][O:52][CH2:53]1.[CH2:9]([CH3:10])[O:11][C:12]([CH2:13][CH2:14][CH2:15][P+:16]([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)([c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1)[c:29]1[cH:30][cH:31][cH:32][cH:33][cH:34]1)=[O:35].[CH3:42][CH2:43][O:44][C:45](=[O:46])[CH3:47].[K+:40].[K+:41].[OH2:54].[n:1]1[c:2]([CH:7]=[O:8])[cH:3][cH:4][cH:5][cH:6]1>>[n:1]1[c:2]([CH:7]=[CH:15][CH2:14][CH2:13][C:12]([O:11][CH2:9][CH3:10])=[O:35])[cH:3][cH:4][cH:5][cH:6]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 962WaterHCID 8857Ethyl AcetateHCID 142732-PyridinecarboxaldehydeHCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 500024Ethyl 4-(triphenylphosphoranyl)butanoate

Product 1

HCID 54207534Ethyl 5-(2-pyridyl)-4-pentenoate

Sources & evidence

ORD record
ord-89ddd09f236c4a439881fc45cb2caeb3
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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