Acetic Acid → 4,6-Dihydroxy-3-phenyl-coumarin

HRID 950392Notes

Reaction equation

HRID 950392 reaction equation
[BrH:21].[CH3:1][O:2][c:3]1[cH:4][c:5]2[c:6]([OH:20])[c:7](-[c:14]3[cH:15][cH:16][cH:17][cH:18][cH:19]3)[c:8](=[O:13])[o:9][c:10]2[cH:11][cH:12]1.[CH3:22][C:23]([O:24][C:25](=[O:26])[CH3:27])=[O:28].[CH3:42][C:43](=[O:44])[OH:45].[CH:29]([O:30][CH:31]([CH3:32])[CH3:33])([CH3:34])[CH3:35].[O:36]1[CH2:37][CH2:38][O:39][CH2:40][CH2:41]1>>[OH:2][c:3]1[cH:4][c:5]2[c:6]([OH:20])[c:7](-[c:14]3[cH:15][cH:16][cH:17][cH:18][cH:19]3)[c:8](=[O:13])[o:9][c:10]2[cH:11][cH:12]1

Participants

7

Reactant 6

HCID 176Acetic AcidHCID 260Hydrogen BromideHCID 7914Diisopropyl EtherHCID 7918Acetic AnhydrideHCID 312751,4-DioxaneHCID 547058964-Hydroxy-6-methoxy-3-phenyl-2H-1-benzopyran-2-one

Product 1

HCID 547213354,6-Dihydroxy-3-phenyl-coumarin

Sources & evidence

ORD record
ord-01e70fb000e64fb7a217bcf39f94d089
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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