Carbon Dioxide → 4,4-Dimethyl-7-carboxythiochroman
Reaction equation
[Br:1][c:2]1[cH:3][c:4]2[c:5]([cH:12][cH:13]1)[C:6]([CH3:10])([CH3:11])[CH2:7][CH2:8][S:9]2.[CH2:14]([Li:15])[CH2:16][CH2:17][CH3:18].[CH3:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33].[ClH:22].[O:19]=[C:20]=[O:21].[O:23]1[CH2:24][CH2:25][CH2:26][CH2:27]1>>[c:2]1([C:20](=[O:19])[OH:21])[cH:3][c:4]2[c:5]([cH:12][cH:13]1)[C:6]([CH3:10])([CH3:11])[CH2:7][CH2:8][S:9]2Participants
7
Sources & evidence
- ORD record
- ord-f10058191d754cba984708c845f2abfe
- Source dataset
- Validation data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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