HRID955150

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID260

Hydrogen Bromide

BrH

HCID6342

Acetonitrile

C2H3N

HCID11776

Triphenylphosphine

C18H15P

结构：CC(C)c1c(C(=O)NCc2ccccc2)nn(-c2ccc(F)cc2)c1CO

HCID24754975

未命名化合物

PRODUCTS

生成物

HCID259

Bromide

Br-

结构：CC(C)c1c(C(=O)NCc2ccccc2)nn(-c2ccc(F)cc2)c1C[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID24755050

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-437b3d635fba4ce79553c312fc2398b8
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[BrH:28].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[NH:8][C:9](=[O:10])[c:11]1[n:12][n:13](-[c:21]2[cH:22][cH:23][c:24]([F:27])[cH:25][cH:26]2)[c:14]([CH2:19][OH:20])[c:15]1[CH:16]([CH3:17])[CH3:18].[CH3:48][C:49]#[N:50].[c:29]1([P:35]([c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[c:42]2[cH:43][cH:44][cH:45][cH:46][cH:47]2)[cH:30][cH:31][cH:32][cH:33][cH:34]1>>[Br-:28].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[NH:8][C:9](=[O:10])[c:11]1[n:12][n:13](-[c:21]2[cH:22][cH:23][c:24]([F:27])[cH:25][cH:26]2)[c:14]([CH2:19][P+:35]([c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)([c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[c:42]2[cH:43][cH:44][cH:45][cH:46][cH:47]2)[c:15]1[CH:16]([CH3:17])[CH3:18]