Acetone → Methyl 6-methoxycarbonylmethoxy-2-naphthoate

HRID 956696Notes

Reaction equation

HRID 956696 reaction equation
[Br:22][CH2:23][C:24](=[O:25])[O:26][CH3:27].[C:16](=[O:17])([O-:18])[O-:19].[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]2[cH:8][cH:9][c:10]([OH:15])[cH:11][c:12]2[cH:13][cH:14]1.[CH3:28][C:29](=[O:30])[CH3:31].[CH3:32][CH2:33][O:34][C:35]([CH3:36])=[O:37].[Cs+:20].[Cs+:21]>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]2[cH:8][cH:9][c:10]([O:15][CH2:23][C:24](=[O:25])[O:26][CH3:27])[cH:11][c:12]2[cH:13][cH:14]1

Participants

7

Reactant 6

HCID 180AcetoneHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 60984Methyl bromoacetateHCID 104967Cesium cation2×HCID 390995Methyl 6-hydroxy-2-naphthoate

Product 1

HCID 18702924Methyl 6-methoxycarbonylmethoxy-2-naphthoate

Sources & evidence

ORD record
ord-bb0a88041b4d418e8576ac558dc560f6
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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