Bicarbonate Ion → tert-butyl N-methyl-N-(3-oxopropyl)carbamate

HRID 957181Notes

Reaction equation

HRID 957181 reaction equation
[C:25](=[O:26])([O-:27])[OH:28].[CH3:1][C:2]1([CH3:11])[N:3]([O:4])[C:5]([CH3:6])([CH3:7])[CH2:8][CH2:9][CH2:10]1.[CH3:37][CH2:38][O:39][C:40]([CH3:41])=[O:42].[CH3:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48].[Cl:30][O-:31].[Cl:33][CH2:34][Cl:35].[Na+:29].[Na+:32].[OH2:36].[OH:12][CH2:13][CH2:14][CH2:15][N:16]([C:17]([O:18][C:19]([CH3:20])([CH3:21])[CH3:22])=[O:23])[CH3:24]>>[O:12]=[CH:13][CH2:14][CH2:15][N:16]([C:17]([O:18][C:19]([CH3:20])([CH3:21])[CH3:22])=[O:23])[CH3:24]

Participants

10

Reactant 9

HCID 769Bicarbonate IonHCID 923Sodium ion2×HCID 962WaterHCID 6344DichloromethaneHCID 8058HexaneHCID 8857Ethyl AcetateHCID 61739HypochloriteHCID 5499762,2,6,6-Tetramethylpiperidin-1-olHCID 10375241tert-Butyl (3-hydroxypropyl)methylcarbamate

Product 1

HCID 10442454tert-butyl N-methyl-N-(3-oxopropyl)carbamate

Sources & evidence

ORD record
ord-2ea984fd08ec4607a83f567fee903702
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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