Dimethyl Sulfoxide → Ethyl [(5-oxopentyl)oxy]acetate

HRID 959426Notes

Reaction equation

HRID 959426 reaction equation
[CH3:1][S:2]([CH3:3])=[O:4].[CH3:31][CH2:32][N:33]([CH2:34][CH3:35])[CH2:36][CH3:37].[Cl:38][CH2:39][Cl:40].[F:5][C:6]([F:7])([F:8])[C:9]([O:10][C:11](=[O:12])[C:13]([F:14])([F:15])[F:16])=[O:17].[OH:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][O:24][CH2:25][C:26](=[O:27])[O:28][CH2:29][CH3:30]>>[O:18]=[CH:19][CH2:20][CH2:21][CH2:22][CH2:23][O:24][CH2:25][C:26](=[O:27])[O:28][CH2:29][CH3:30]

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 9845Trifluoroacetic anhydrideHCID 14254559Ethyl [(5-hydroxypentyl)oxy]acetate

Product 1

HCID 14254560Ethyl [(5-oxopentyl)oxy]acetate

Sources & evidence

ORD record
ord-4e39957d509d465d8e683ebdf5bf6503
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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