Sodium ion → 5-Benzylthiomethyl-5-t-butyl-2,2-dimethyl-1,3-dioxane

HRID 960146Notes

Reaction equation

HRID 960146 reaction equation
[C:16]([CH3:17])([CH3:18])([CH3:19])[C:20]1([CH2:28][OH:29])[CH2:21][O:22][C:23]([CH3:26])([CH3:27])[O:24][CH2:25]1.[CH2:3]([c:4]1[cH:5][cH:6][cH:7][cH:8][cH:9]1)[SH:10].[CH3:11][S:12]([OH:13])(=[O:14])=[O:15].[CH3:31][N:32]([CH3:33])[CH:34]=[O:35].[H-:1].[Na+:2].[OH2:30]>>[CH2:3]([c:4]1[cH:5][cH:6][cH:7][cH:8][cH:9]1)[S:10][CH2:28][C:20]1([C:16]([CH3:17])([CH3:18])[CH3:19])[CH2:21][O:22][C:23]([CH3:26])([CH3:27])[O:24][CH2:25]1

Participants

8

Reactant 7

HCID 923Sodium ionHCID 962WaterHCID 6228DimethylformamideHCID 6395Methanesulfonic AcidHCID 7509Benzyl mercaptanHCID 166653HydrideHCID 20075570(5-Tert-butyl-2,2-dimethyl-1,3-dioxan-5-yl)methanol

Product 1

HCID 200755965-Benzylthiomethyl-5-t-butyl-2,2-dimethyl-1,3-dioxane

Sources & evidence

ORD record
ord-a0e9d8256e724dd981f1f7567ce002ad
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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