Acetate → 3-(3-Methoxycarbonylphenyl)benzoic acid

HRID 961597Notes

Reaction equation

HRID 961597 reaction equation
[C:24](=[O:25])([O-:26])[O-:27].[CH3:11][O:12][C:13](=[O:14])[c:15]1[cH:16][c:17]([B:21]([OH:22])[OH:23])[cH:18][cH:19][cH:20]1.[ClH:30].[Cs+:28].[Cs+:29].[I:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][cH:9][cH:10]1.[O-:37][C:38]([CH3:39])=[O:40].[O-:41][C:42]([CH3:43])=[O:44].[O:31]=[CH:32][N:33]([CH3:34])[CH3:35].[OH2:45].[Pd+2:36]>>[c:2]1(-[c:17]2[cH:16][c:15]([C:13]([O:12][CH3:11])=[O:14])[cH:20][cH:19][cH:18]2)[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][cH:9][cH:10]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 313Hydrochloric AcidHCID 962WaterHCID 6228DimethylformamideHCID 120603-Iodobenzoic acidHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27347143-(Methoxycarbonyl)benzeneboronic acid

Product 1

HCID 201001193-(3-Methoxycarbonylphenyl)benzoic acid

Sources & evidence

ORD record
ord-77990b0764764666b155b32464874938
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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