Potassium Cation → 6-Bromo-2H-1,3-benzodioxole-4-carbaldehyde

HRID 961976Notes

Reaction equation

HRID 961976 reaction equation
[Br:1][c:2]1[cH:3][c:4]([OH:11])[c:5]([OH:10])[c:6]([CH:7]=[O:8])[cH:9]1.[C:12](=[O:13])([O-:14])[O-:15].[CH3:21][N:22]([CH3:23])[CH:24]=[O:25].[I:18][CH2:19][I:20].[K+:16].[K+:17]>>[Br:1][c:2]1[cH:3][c:4]2[c:5]([c:6]([CH:7]=[O:8])[cH:9]1)[O:10][CH2:12][O:11]2

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 6346DiiodomethaneHCID 19660Carbonate IonHCID 186155855-Bromo-2,3-dihydroxybenzaldehyde

Product 1

HCID 125140976-Bromo-2H-1,3-benzodioxole-4-carbaldehyde

Sources & evidence

ORD record
ord-4fa66e6ad0a94d0bae79882451e2dd31
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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