Azobisisobutyronitrile → HCID 86605409, compound

HRID 968462Notes

Reaction equation

HRID 968462 reaction equation
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]1(=[O:16])[O:15][C:13](=[O:14])[CH:12]=[CH:11]1.[F:17][C:18]([F:57])([S:41]([O:44][N:45]1[C:54](=[O:55])[C:53]2[CH:52]3[CH2:56][CH:49]([CH2:50][CH2:51]3)[C:48]=2[C:46]1=[O:47])(=[O:43])=[O:42])[C:19]([F:40])([F:39])[C:20]([F:38])([F:37])[C:21]([F:36])([F:35])[C:22]([F:34])([F:33])[C:23]([F:32])([F:31])[C:24]([F:30])([F:29])[C:25]([F:28])([F:27])[F:26].CC(N=NC(C#N)(C)C)(C#N)C>CC(C)=O>[CH3:10][CH:11]=[C:7]([CH3:8])[C:6]([OH:5])=[O:9].[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:13]1(=[O:14])[O:15][C:10](=[O:16])[CH:11]=[CH:12]1.[F:57][C:18]([F:17])([S:41]([O:44][N:45]1[C:46](=[O:47])[C:48]2[CH:49]3[CH2:56][CH:52]([CH2:51][CH2:50]3)[C:53]=2[C:54]1=[O:55])(=[O:42])=[O:43])[C:19]([F:39])([F:40])[C:20]([F:37])([F:38])[C:21]([F:35])([F:36])[C:22]([F:34])([F:33])[C:23]([F:32])([F:31])[C:24]([F:30])([F:29])[C:25]([F:28])([F:27])[F:26]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 7923Maleic AnhydrideHCID 15458tert-Butyl acrylateHCID 76498487HCID 76498487, compound

Product 1

HCID 86605409HCID 86605409, compoundYield 78%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

2.0 g of methylmethacryilic acid, 9.0 g of t-butylacrylate, 1.0 g of maleic anhydride, 1.2 g of N-[(perfluorooctanesulfonyl)oxy]-norbornene-2,3-dicarboximide and 0.5 g of AIBN were dissolved in 50 g of acetone. The monomers were polymerized at 67° C. for 6 hours. After completion of the polymerization, the polymerized product was precipitated in water, filtered, and dried in a vacuum to give poly(methylmethacrylic acid-t-butylacrylate-maleic anhydride-N-[(perfluorooctanesulfonyl)oxy]-norbornene-2,3-dicarboximide) in a yield of 78%. The structure of the polymer was identified by 1H-NMR spectroscopy (FIG. 1).

Workup

  1. customThe monomers were polymerized at 67° C. for 6 hours
  2. customAfter completion of the polymerization
  3. customthe polymerized product was precipitated in water
  4. filtrationfiltered
  5. customdried in a vacuum

Sources & evidence

ORD record
ord-1fd61f07b4db4307a2d06c5efcf64cc1
Source dataset
uspto-grants-2007_12
Patent number
US07303858B2

Reaction notes

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