Sodium hydride → 4-Chlorobenzaldehyde

HRID 972341Notes

Reaction equation

HRID 972341 reaction equation
[H-].[Na+].[I-].C[S+](C)C.[Cl:8][C:9]1[CH:17]=[CH:16][C:12]([CH:13]2[O:15]C2)=[CH:11][CH:10]=1>>[Cl:8][C:9]1[CH:17]=[CH:16][C:12]([CH:13]=[O:15])=[CH:11][CH:10]=1

Participants

4

Reactant 3

HCID 24758Sodium hydrideHCID 75127Trimethylsulfonium iodideHCID 1970104-Chlorostyrene oxide

Product 1

HCID 77264-Chlorobenzaldehyde

Procedure

Following the procedure of Example 6 and employing 42.0 g. of 57% sodium hydride/mineral oil, 200 g. (1.0 mol) of trimethylsulfonium iodide and 70.4 g. (0.50 mol) of p-chlorobenzaldehyde there is obtained p-chlorostyrene oxide.

Sources & evidence

ORD record
ord-79de12da5d0e4d13b4f0a96de2d96996
Source dataset
uspto-grants-1977_10
Patent number
US04052506

Reaction notes

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