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HRID974716

反应详情

EQUATION

反应方程式

HRID 974716 的结构方程式

REACTANTS

反应物

3
结构：Nc1ccc(O)cc1
HCID403

4-Aminophenol

C6H7NO

结构：[Cl-].[Na+]
HCID5234

Sodium chloride

ClNa

结构：Nc1c(S(=O)(=O)O)cc(Br)c2c1C(=O)c1ccccc1C2=O
HCID22628

1-Amino-4-bromo-9,10-dioxo-9,10-dihydroanthracene-2-sulfonic acid

C14H8BrNO5S

PRODUCTS

生成物

1
结构：Nc1c(S(=O)(=O)O)cc(Nc2ccc(O)cc2)c2c1C(=O)c1ccccc1C2=O
HCID106250

2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-[(4-hydroxyphenyl)amino]-9,10-dioxo-

C20H14N2O6S

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=S(=O)([O-])[O-].[Cu+2]
催化剂HCID24462

Copper sulfate

CuO4S

CONDITIONS

反应条件

温度
60 °C

PROCEDURE

实验过程

38.2 parts of 1-amino-4-bromo-2-sulfoanthraquinone (bromamine acid) are condensed in an aqueous suspension with 12.7 parts of 4-aminophenol with the addition of 1 part of copper(II) sulfate at a pH of 8.5 and a temperature of 70° C. over a period of 1 to 2 hours. This results in a dark blue solution. After cooling to 20°-25° C., the reaction mixture is acidified until reaching a pH of about 1, stirred at 60° C. for about 1 h, salted out with sodium chloride, and the dye chromophore 4-(4'-hydroxyphenyl)amino-1-amino-2-sulfoanthraquinone is isolated by suction filtration.

WORKUP

后处理

  1. customThis results in a dark blue solution
  2. temperatureAfter cooling to 20°-25° C.