Hydrazoic acid → HCID 178427292, compound

HRID 978189Notes

Reaction equation

HRID 978189 reaction equation
[C:1]1([CH3:12])[CH:6]=[CH:5][C:4]([S:7]([C:10]#[N:11])(=[O:9])=[O:8])=[CH:3][CH:2]=1.[NH:13]=[N+:14]=[N-:15]>C1C=CC=CC=1>[C:1]1([CH3:12])[CH:2]=[CH:3][C:4]([S:7]([C:10]2[NH:15][N:14]=[N:13][N:11]=2)(=[O:8])=[O:9])=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 24530Hydrazoic acidHCID 87946p-Toluenesulphonyl cyanide

Product 1

HCID 178427292HCID 178427292, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A mixture of p-toluenesulfonyl cyanide (0.0 g.) and excess hydrazoic acid in 50 ml. of benzene is stirred at room temperature for 20 hours. The product is filtered off, dissolved in ether, filtered through celite and evaporated to a solid which on trituration with benzene has a melting point, 133°-135° C.

Workup

  1. filtrationThe product is filtered off
  2. dissolutiondissolved in ether
  3. filtrationfiltered through celite
  4. customevaporated to a solid which on trituration with benzene
  5. customa melting point, 133°-135° C.

Sources & evidence

ORD record
ord-af4679b8e3c64a1a8be2e3fe735041f1
Source dataset
uspto-grants-1987_05
Patent number
US04663461

Reaction notes

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