Water → HCID 178486779, compound

HRID 979312Notes

Reaction equation

HRID 979312 reaction equation
Br[C:2]1[C:15]2[S:14](=[O:17])(=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[C:11]([O:18][CH3:19])[CH:12]=3)[NH:7][C:6]=2[CH:5]=[C:4]([O:20][CH3:21])[C:3]=1[OH:22].O.ClC1C(=O)C(C#N)=C(C#N)C(=[O:32])C=1Cl.CCCCCC>C1COCC1>[OH:32][C:2]1[C:3](=[O:22])[C:4]([O:20][CH3:21])=[CH:5][C:6]2[C:15]=1[S:14](=[O:17])(=[O:16])[C:13]1[C:8](=[CH:9][CH:10]=[C:11]([O:18][CH3:19])[CH:12]=1)[N:7]=2

Participants

6

Reactant 4

HCID 962WaterHCID 67752,3-Dichloro-5,6-dicyano-1,4-benzoquinoneHCID 8058HexaneHCID 13853740HCID 13853740, compound

Product 1

HCID 178486779HCID 178486779, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a stirred suspension of 4-bromo-3-hydroxy-2,7-dimethoxy-10H-phenothiazine-5,5-dioxide (100 mg) in THF (10 ml) was added water (0.1 ml) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (0.12 g). After 20 minutes, hexane was added and the solid was filtered, washed with ether and air dried to afford the title compound, m.p. 333°-335° C. (dec.)

Workup

  1. filtrationthe solid was filtered
  2. washwashed with ether and air
  3. customdried

Sources & evidence

ORD record
ord-a33911a637a34fa8a4144ba13e9b57b4
Source dataset
uspto-grants-1987_05
Patent number
US04667032

Reaction notes

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