Hydrogen Peroxide → Hydrogen Peroxide

HRID 979750Notes

Reaction equation

HRID 979750 reaction equation
[C:1]([NH:12][C:13]1[CH:18]=[CH:17][C:16]([CH2:19][C:20]([OH:22])=[O:21])=[CH:15][CH:14]=1)(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[OH:23][OH:24]>CS(O)(=O)=O>[C:1]([NH:12][C:13]1[CH:18]=[CH:17][C:16]([CH2:19][C:20]([OH:22])=[O:21])=[CH:15][CH:14]=1)(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[OH:23][OH:24].[C:1]([NH:12][C:13]1[CH:18]=[CH:17][C:16]([CH2:19][C:20]([O:22][OH:23])=[O:21])=[CH:15][CH:14]=1)(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

6

Reactant 2

HCID 784Hydrogen PeroxideHCID 21231018HCID 21231018, compound

Product 3

HCID 784Hydrogen PeroxideHCID 21231018HCID 21231018, compoundHCID 53834230HCID 53834230, compound

Reagents, catalysts & solvents 1

HCID 6395Methanesulfonic AcidSolvent2×

Procedure

N-Decanoyl-4-aminophenylperoxyacetic acid was prepared from N-decanoyl-4-aminophenylacetic acid and hydrogen peroxide in methanesulfonic acid according to the procedure described in Example II. From 70.0 g (0.229 mol) of N-decanoyl-4-aminophenylacetic acid and 39.0 g (1.15 mol) of hydrogen peroxide in 150 mL 98% methanesulfonic acid was obtained 64.9 g of N-decanoyl-4-aminophenylperoxyacetic acid having an AvO of 4.94% (theoretical yield=73.6 g gaving an AvO of 4.99%), mp 121° C.

Sources & evidence

ORD record
ord-d962b0ebd1244a10959a5bfd75b462da
Source dataset
uspto-grants-1987_01
Patent number
US04634551

Reaction notes

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