Isopropanol → HCID 86741194, compound

HRID 980027Notes

Reaction equation

HRID 980027 reaction equation
CC(C[Al](CC(C)C)CC(C)C)C.[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]>CCCCCCC.C1CCCCC1>[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]

Participants

6

Reactant 3

HCID 3776IsopropanolHCID 77452-Methyl-1-pentanolHCID 16682931Triisobutylaluminum

Product 1

HCID 86741194HCID 86741194, compound

Reagents, catalysts & solvents 2

HCID 8078CyclohexaneSolventHCID 8900HeptaneSolvent

Procedure

To 10 ml of 1.085M DBM in heptane containing 0.33 ml of 0.92M TIBAL is added slowly a mixture of 2-methyl-1-pentanol (1.80 ml, 14.45 mmoles) and isopropanol (0.55 ml, 7.25 mmoles) diluted to 5 ml with cyclohexane. The solution remains clear throughout the addition (no precipitate formation) and is crystal-clear and somewhat viscous at room temperature.

Workup

  1. additionThe solution remains clear throughout the addition (no precipitate formation) and
  2. customis crystal-clear and somewhat viscous at room temperature

Sources & evidence

ORD record
ord-3e37218478134bd58e3d0133c36045c2
Source dataset
uspto-grants-1987_01
Patent number
US04634786

Reaction notes

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