Diisobutylaluminum hydride → HCID 54279535, compound

HRID 981016Notes

Reaction equation

HRID 981016 reaction equation
[CH:1]([CH:4]1[O:18][CH:17]2[CH:6]([CH2:7][CH2:8][CH:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH2:15][CH2:16]2)[O:5]1)([CH3:3])[CH3:2].CC(C[AlH]CC(C)C)C>C1(C)C=CC=CC=1>[CH2:4]([O:5][CH:6]1[CH:17]([OH:18])[CH2:16][CH2:15][CH:14]=[CH:13][CH2:12][CH2:11][CH:10]=[CH:9][CH2:8][CH2:7]1)[CH:1]([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 14487Diisobutylaluminum hydrideHCID 54568910HCID 54568910, compound

Product 1

HCID 54279535HCID 54279535, compoundYield 79%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The same procedure as that described in example 2(b) was followed but using 5.92 g of 14-isopropyl-13,15-dioxabicyclo[10.3.0]pentadeca-4,8-diene and 39.5 ml of a 1.2M solution of DIBAH in toluene. 4.71 g of 12-isobutoxy-4,8-cyclododecadien-1-ol were obtained.

Sources & evidence

ORD record
ord-0872ad5591d04a3787cf507f02cde8e7
Source dataset
uspto-grants-1991_02
Patent number
US04990495

Reaction notes

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