HCID 86741952, compound → HCID 55283956, compound

HRID 986740Notes

Reaction equation

HRID 986740 reaction equation
[N:1]([C@H:4]([C@H:8]([N:11]=[N+]=[N-])[CH2:9][OH:10])[CH2:5][CH2:6][OH:7])=[N+]=[N-]>C(O)C.[Pt](=O)=O>[NH2:1][C@H:4]([C@H:8]([NH2:11])[CH2:9][OH:10])[CH2:5][CH2:6][OH:7]

Participants

4

Reactant 1

HCID 86741952HCID 86741952, compound

Product 1

HCID 55283956HCID 55283956, compound

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 702EthanolSolvent

Procedure

A 10 g portion of 3,4-diazido-2,3,4-trideoxy-D-erythro-pentitol, dibenzeate was dissolved in 35 ml of ethanol, a 1.8 g portion of platinum dioxide added and the mixture reduced in a Parr shaker overnight. The catalyst was removed by filtration and the filtrate evaporated to dryness, giving 4.36 g of 3,4-diamino-2,3,4-trideoxy-D-erythro-pentitol, 1,5-dibenzerate.

Workup

  1. customreduced in a Parr shaker overnight
  2. customThe catalyst was removed by filtration
  3. customthe filtrate evaporated to dryness

Sources & evidence

ORD record
ord-6b5275caae7b4f768758f2852e1d84e3
Source dataset
uspto-grants-1987_12
Patent number
US04716157

Reaction notes

Loading…