Hydrochloric Acid → Cyclopentanecarboxaldehyde, 2,2,5,5-tetramethyl-

HRID 986862Notes

Reaction equation

HRID 986862 reaction equation
C[O:2][CH:3]=[C:4]1[C:8]([CH3:10])([CH3:9])[CH2:7][CH2:6][C:5]1([CH3:12])[CH3:11].Cl>O1CCCC1>[CH:3]([CH:4]1[C:5]([CH3:12])([CH3:11])[CH2:6][CH2:7][C:8]1([CH3:10])[CH3:9])=[O:2]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 139229422,2,5,5-Tetramethylcyclopentylidenemethyl methyl ether

Product 1

HCID 9793878Cyclopentanecarboxaldehyde, 2,2,5,5-tetramethyl-Yield 94%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

10 g of 2,2,5,5-tetramethylcyclopentylidenemethyl methyl ether was dissolved in 100 ml of tetrahydrofuran, and 50 ml of 6N-hydrochloric acid was added thereto. The mixture was vigorously stirred at room temperature for 3 hours, and then treated in the same manner as in Example 11 to obtain 8.60 g of 1-formyl-2,2,5,5-tetramethylcyclopentane. Yield 94%.

Workup

  1. additiontreated in the same manner as in Example 11

Sources & evidence

ORD record
ord-f89d519c1a124042a8d9585b69c8cc0a
Source dataset
uspto-grants-1987_12
Patent number
US04716241

Reaction notes

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