Dimethyl Sulfoxide → 1-Tert-butyl 2-methyl 4-azidopyrrolidine-1,2-dicarboxylate

HRID 99640Notes

Reaction equation

HRID 99640 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH:9]([C:18](=[O:19])[O:20][CH3:21])[CH2:10][CH:11]([O:13][S:14]([CH3:15])(=[O:16])=[O:17])[CH2:12]1.[CH3:26][S:27](=[O:28])[CH3:29].[CH3:30][CH2:31][O:32][C:33](=[O:34])[CH3:35].[N-:23]=[N+:24]=[N-:25].[Na+:22]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH:9]([C:18](=[O:19])[O:20][CH3:21])[CH2:10][CH:11]([N:23]=[N+:24]=[N-:25])[CH2:12]1

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 8857Ethyl AcetateHCID 33558AzideHCID 147726801-Tert-butyl 2-methyl 4-(methanesulfonyloxy)pyrrolidine-1,2-dicarboxylate

Product 1

HCID 147726831-Tert-butyl 2-methyl 4-azidopyrrolidine-1,2-dicarboxylate

Sources & evidence

ORD record
ord-0b2e354bd1d849bab3aa0cf4c13a15ba
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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