对羟基苯甲酸 → Benzoic acid, 4-((1-oxodecyl)oxy)-

HRID 752

反应方程式

HRID 752 反应方程式
[OH:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1.[C:11](Cl)(=[O:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].N1C=CC=CC=1>O>[C:11]([O:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1)(=[O:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

参与物

5

反应物 3

HCID 135对羟基苯甲酸HCID 1049吡啶HCID 66982癸酰氯

产物 1

HCID 3608562Benzoic acid, 4-((1-oxodecyl)oxy)-

试剂、催化剂与溶剂 1

HCID 962聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯]溶剂

实验过程

10 Grams of p-hydroxybenzoic acid and 15 g of decanoic acid chloride were stirred at room temperature, and 7.2 g of pyridine was dropwise added. After the mixture was stirred for 1 day, a reaction product was poured into water, and an organic layer was extracted with dichloromethane. The organic layer was washed with 1N hydrochloric acid and dried over anhydrous sodium sulfate, the solvent was distilled off, and then residue was washed with n-hexane and then dried to give a crude end product.

后处理

  1. extractionan organic layer was extracted with dichloromethane
  2. washThe organic layer was washed with 1N hydrochloric acid
  3. dry with materialdried over anhydrous sodium sulfate
  4. distillationthe solvent was distilled off
  5. washresidue was washed with n-hexane
  6. customdried
  7. customto give a crude end product

来源与证据

ORD记录
ord-c218088b16c541088a933a7606f68c4c
来源数据集
uspto-grants-1998_03
专利号
US05723069

关联笔记

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