Kaliummethanolat

Potassium methoxide

HCID 23664618CAS 865-33-8

Grundinformationen

Standard-SMILES
C[O-].[K+]
InChIKey
BDAWXSQJJCIFIK-UHFFFAOYSA-N
Summenformel
CH3OK
Durchschnittliche Molmasse
70,132 g/mol
Monoisotopische Masse
69,9820964

Namen und Bezeichner

Bevorzugter Name
Potassium methoxide
IUPAC
potassium methanolate
Lokaler Name
Kaliummethanolat
Englischer Name
Potassium methoxide
Summenformel
CH3KO
Molmasse
70.13

Namen und Synonyme

Potassium methoxide865-33-8Potassium methanolatePotassium methylateMethanol, potassium salt45MYQ0GWGBMethanol, potassium salt (1:1)DTXSID1029627Methoxy potassiumRefChem:867893DTXCID509627212-736-1
Weitere Namen anzeigen
potassium methoxide solutionKaliummethanolatMethanol,potassiumsaltPotassiuM Methoxide 95%PotassiummethoxidesolidHPLC Potassium methoxidePotassium methoxide, 90+%Potassiummethoxide,95-99%
potassium;methanolateMFCD00012416METHOXYPOTASSIUMUNII-45MYQ0GWGBEC 212-736-1KOMeMeOKEINECS 212-736-1

Datenbank-Bezeichner

CAS
865-33-8
PubChem CID
23664618
DTXSID
DTXSID1029627
UNII
45MYQ0GWGB
EC Number
212-736-1
Nikkaji
J195.129G

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
23,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
3

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metal Alkoxides
LogP-0.74
Density1.7 g/cm³
SolubilitySolubility in water: reaction
Flash Point11 °C c.c.
Melting PointNo melting point; decomposes at >50 °C

Physikochemische Eigenschaften

Schmelzpunkt
-20 °C · -20°C
Siedepunkt
84 °C · 84°C
Dichte
0.95 g/mL · 0.95 g/mL at 20 °C
Dampfdruck
0 Pa · 0Pa at 25℃
Brechungsindex
20 · n20/D 1.37
Flammpunkt
7 °C · 7°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H251: Self-heating; may catch fire [Danger Self-heating substances and mixtures]

P235, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 0.4% (1 of 233) of reports.

Danger

H228 (50.6%): Flammable solid [Danger Flammable solids]

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Methanol, potassium salt

Methanol, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanol, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 03-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/13210

Methanol, Potassium Salt: HSNO Approval: HSR007896 Approved with controls

Fire HazardsHighly flammable. Many reactions may cause fire or explosion. Risk of fire and explosion on contact with water, moisture or metals.
Hazards Summary · 1 Eintrag

Rapidly and exothermically reacts with tissue water forming potassium hydroxide (responsible for corrosivity) and methanol; Not likely to cause skin sensitization or be carcinogenic; [OECD SIDS: Methanolates - 2006] Reacts violently with water; Self-heating, may catch fire; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Methyl alcohol. See Potassium hydroxide. See Sodium methylate.

EC ClassificationSymbol: F, C; R: 11-14-34; S: (1/2)-8-16-26-43-45
UN ClassificationUN Hazard Class: 4.2; UN Subsidiary Risks: 8
Chemical Dangers · 1 Eintrag

Heating may cause violent combustion or explosion. Reacts violently with water. This produces flammable methanol and corrosive potassium hydroxide. The substance may ignite spontaneously on contact with moist air. The substance is a strong reducing agent. It reacts violently with oxidants. The substance is a strong base. It reacts violently with acid and is corrosive. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001).

Sicherheit und Schutzausrüstung

Fire FightingNO water. NO hydrous agents. Use dry powder, dry sand. In case of fire: keep cylinder cool by spraying with water. NO direct contact of the substance with water.
First Aid Measures · 4 Einträge

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.

First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer immediately for medical attention.

Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.

Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

Safe StorageFireproof. Separated from strong oxidants, acids, metals and food and feedstuffs. Dry. Cool. Well closed. Store in an area having corrosion resistant concrete floor. Store in an area without drain or sewer access.
Spillage Disposal · 1 Eintrag

Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into covered dry plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Eye PreventionWear face shield or eye protection in combination with breathing protection.
Fire PreventionNO open flames, NO sparks and NO smoking. NO contact with water.

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesSerious local effects by all routes of exposure.
Signs and Symptoms · 4 Einträge

Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing.

Redness. Pain. Serious skin burns.

Redness. Pain. Blurred vision. Severe deep burns.

Burns in mouth and throat. Burning sensation in the throat and chest. Shock or collapse.

ICSC Environmental DataThis substance may be hazardous to the environment. Special attention should be given to aquatic organisms.

Sicherheitsdaten

F
3-10-23
wgk
1
tsca
TSCA listed
ridadr
UN 3274 3/PG 2
hs_code
29051900
risk_code
11-14-34-67-65-63-48/20-39/23/24/25-38-23/24/25

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as a chemical intermediate and in biodiesel production; [OECD SIDS: Methanolates - 2006]
U.S. Production2023: <50,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

All Other Chemical Product and Preparation Manufacturing

Methanol, potassium salt (1:1): ACTIVE

Anwendungen · 1 Eintrag

VerwendenPotassium methoxide is used as a chemical intermediate. It is also used in biodiesel production and in fuel additives. It acts as a catalyst for the preparation of methyl formate and an alkaline catalyst for dimethyl formamide. Further, it is used as versatile reagents in chemical reactions such as condensation, esterification, alkoxylation and etherification, Claisen condensation, Wolf-Kishner reduction and Stobbe reaction.

Anbieter50 Anbieter

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Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]

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