Grundinformationen
- Standard-SMILES
C[O-].[K+]- InChIKey
BDAWXSQJJCIFIK-UHFFFAOYSA-N- Summenformel
- CH3OK
- Durchschnittliche Molmasse
- 70,132 g/mol
- Monoisotopische Masse
- 69,9820964
Namen und Bezeichner
- Bevorzugter Name
- Potassium methoxide
- IUPAC
- potassium methanolate
- Lokaler Name
- Kaliummethanolat
- Englischer Name
- Potassium methoxide
- Summenformel
- CH3KO
- Molmasse
- 70.13
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
865-33-8- PubChem CID
- 23664618
- DTXSID
DTXSID1029627- UNII
- 45MYQ0GWGB
- EC Number
- 212-736-1
- Nikkaji
- J195.129G
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 23,1 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 1
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 3
- Formalladung
- 0
- Komplexität
- 4,8
Experimentelle und physikochemische Eigenschaften
Vapor Pressure
0.0000048 [mmHg]
Vapor pressure, Pa at 25 °C: (negligible)
Physical Description
Liquid
White to yellow hygroscopic solid; [Reference #1] Commercial products are powders or 32% solutions in methanol; [Reference #2] White powder; [Alfa Aesar MSDS]
WHITE-TO-YELLOW HYGROSCOPIC POWDER.
Physikochemische Eigenschaften
- Schmelzpunkt
- -20 °C · -20°C
- Siedepunkt
- 84 °C · 84°C
- Dichte
- 0.95 g/mL · 0.95 g/mL at 20 °C
- Dampfdruck
- 0 Pa · 0Pa at 25℃
- Brechungsindex
- 20 · n20/D 1.37
- Flammpunkt
- 7 °C · 7°C
- storage temp.
- 30 °C · Store below +30°C.
- Löslichkeit
- Soluble in methanol and ethanol.
- pka
- 15.17 · 15.17[at 20 ℃]
- Aggregatzustand
- Liquid
- Farbe
- Clear colorless
- Wichte
- 0.95 · 0.95
- PH
- 12.8 · 12.8 (7g/l, H2O, 20℃)
- Wasserlöslichkeit
- may decompose
- BRN
- 3551544 · 3551544
- Stabilität
- Stable. Reacts violently with water. Moisture sensitive. Absorbs carbon dioxide from the air. Incompatible with acids, strong oxidizing agents, acid chlorides, acid anhydrides, alkali metals.
- InChI
- 1S/CH3O.K/c1-2;/h1H3;/q-1;+1
- InChIKey
- BDAWXSQJJCIFIK-UHFFFAOYSA-N
- SMILES
- [K+].C[O-]
- CAS Datenbank
- 865 · 865-33-8(CAS DataBase Reference)
- EPA chemische Informationen
- Methanol, potassium salt (865-33-8)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H251: Self-heating; may catch fire [Danger Self-heating substances and mixtures]
P235, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)
This chemical does not meet GHS hazard criteria for 0.4% (1 of 233) of reports.
Danger
H228 (50.6%): Flammable solid [Danger Flammable solids]
Gefahrenhinweise
Regulatory Information
Chemical: Methanol, potassium salt
Methanol, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanol, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 03-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/13210
Methanol, Potassium Salt: HSNO Approval: HSR007896 Approved with controls
Hazards Summary
Rapidly and exothermically reacts with tissue water forming potassium hydroxide (responsible for corrosivity) and methanol; Not likely to cause skin sensitization or be carcinogenic; [OECD SIDS: Methanolates - 2006] Reacts violently with water; Self-heating, may catch fire; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Methyl alcohol. See Potassium hydroxide. See Sodium methylate.
Chemical Dangers
Heating may cause violent combustion or explosion. Reacts violently with water. This produces flammable methanol and corrosive potassium hydroxide. The substance may ignite spontaneously on contact with moist air. The substance is a strong reducing agent. It reacts violently with oxidants. The substance is a strong base. It reacts violently with acid and is corrosive. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001).
Hazard Classes and Categories
Flam. Sol. 1 (50.6%)
Self-heating substance or mixture - category 1
Self-heat. 1
Sicherheit und Schutzausrüstung
First Aid Measures
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.
First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer immediately for medical attention.
Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.
Spillage Disposal
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into covered dry plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT wash away into sewer.
Toxikologische Informationen
Signs and Symptoms
Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing.
Redness. Pain. Serious skin burns.
Redness. Pain. Blurred vision. Severe deep burns.
Burns in mouth and throat. Burning sensation in the throat and chest. Shock or collapse.
Sicherheitsdaten
- F
- 3-10-23
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 3274 3/PG 2
- hs_code
- 29051900
- risk_code
- 11-14-34-67-65-63-48/20-39/23/24/25-38-23/24/25
- hazard_code
- F,T,C
- safety_code
- 8-16-26-43-45-62-46-36/37/39-33-29-25
- hazard_class
- 4.2
- packing_group
- II
- Speicherklasse
- 4.2 - Pyrophoric and self-heating hazardous materials
- Hazard Classifications
- Self-heat. 1Skin Corr. 1B
- Selbstentzündungstemperatur
- 30 - 50 °C
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Methanol, potassium salt (1:1): ACTIVE
Anwendungen
VerwendenPotassium methoxide is used as a chemical intermediate. It is also used in biodiesel production and in fuel additives. It acts as a catalyst for the preparation of methyl formate and an alkaline catalyst for dimethyl formamide. Further, it is used as versatile reagents in chemical reactions such as condensation, esterification, alkoxylation and etherification, Claisen condensation, Wolf-Kishner reduction and Stobbe reaction.
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