Oxygen → Tetralin

HRID 1088001

Reaktionsgleichung

[C:1]1(=O)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][CH2:2]1.C1(C)C=CC=CC=1.O=O.C1CC2C(=CC=CC=2)C(O)C1>[OH-].[Cu+2].[OH-].O>[CH2:9]1[C:10]2[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=2)[CH2:6][CH2:7][CH2:8]1

Komponenten

Reaktionsbedingungen

Temperatur: 80 °C

Versuchsvorschrift

Tetralone (132 g), toluene (131 g), and 0.5 g of copper hydroxide suspension (37.5% Cu(OH)2), were mixed into a 500 ml round bottom with temperature control, gas dispersion tube, water-cooled condenser and a magnetic stirrer. The reaction was maintained at 80° C. for 9.8 hr. with a 300 ml/minute oxygen flow at atmospheric pressure. GC analysis (area %) indicates 3% 1-tetralol, 5.2% 1-tetralone and 15% 1-tetralin hydroperoxide.

Aufarbeitung

temperaturecooled condenser and a magnetic stirrer

Quellen und Nachweise

ORD-Eintrag: ord-5d11b18391fb4479a811ec1fe8b4031f
Quelldatensatz: uspto-grants-1990_10
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04960944

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