Carbon Dioxide → Carbon Dioxide

HRID 1581122Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1581122
[O:1]=[P:2]12[O:13][P:11]3([O:14][P:4]([O:6][P:7]([O:10]3)([O:9]1)=[O:8])(=[O:5])[O:3]2)=[O:12].[Al+3].[Cl-:16].[Cl-:17].[Cl-].O=P(Cl)(Cl)Cl.P(Cl)(Cl)Cl.P(Cl)(Cl)(Cl)(Cl)Cl.O=POP=O.[C:39](=[O:41])=[O:40]>>[O:5]=[P:4]12[O:3][P:2]3([O:9][P:7]([O:10][P:11]([O:13]3)([O:14]1)=[O:12])(=[O:8])[O:6]2)=[O:1].[C:39](=[O:41])=[O:40].[Cl:16][Cl:17]

Komponenten

10

Edukt 7

HCID 280Carbon DioxideHCID 14810Phosphorus trioxideHCID 14812Phosphorus oxide (P4O10)HCID 24387Phosphorus trichlorideHCID 24813Phosphorus oxychlorideHCID 24819Phosphorus pentachlorideHCID 6451240Aluminum(III) Chloride2×

Produkt 3

HCID 280Carbon DioxideHCID 14812Phosphorus oxide (P4O10)HCID 24526Chlorine

Versuchsvorschrift

A process of anhydrous carbo-chlorination of AlPO4 comprising the steps of introducing AlPO4 -containing material into a reactor zone; introducing chlorine and carbonaceous material into said reactor zone; heating the reactor zone to a temperature of from 600°-1200°C to form aluminum chlorides, phosphorous oxides, phosphorous chlorides, phosphorous oxychlorides and carbon oxides; separating the reaction products into three fractions by condensation, the first fraction being P2O5, the second fraction being AlCl3 and AlCl3 . POCl3, and the third fraction being PCl3, PCl5, P2O3, CO and CO2 ; and passing said fraction, which is gaseous, into an oxidizer to produce P2O5, CO2 and Cl2.

Aufarbeitung

  1. customseparating the reaction products into three fractions
  2. customby condensation

Quellen und Nachweise

ORD-Eintrag
ord-fa9bbbf90d4e46d5bcc9361ca3f99705
Quelldatensatz
uspto-grants-1976_01
Patentnummer
US03935297

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