Acetic Acid → HCID 21317539, Verbindung

HRID 1833454Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1833454
[Cl:1][CH2:2][CH2:3][S:4][CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26][C:27](=[O:29])[CH3:28])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13].OO.[OH2:32].C(O)(=[O:35])C>CCOCC>[Cl:1][CH2:2][CH2:3][S:4]([CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26][C:27](=[O:29])[CH3:28])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])(=[O:35])=[O:32]

Komponenten

6

Edukt 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 962WaterHCID 21317532Ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate

Produkt 1

HCID 21317539HCID 21317539, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

A solution of ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate (45.1 g., 0.1 mole) and 30% aqueous hydrogen peroxide (50 ml.) in acetic acid (225 ml.) is allowed to stand 20 hours at 25° C. The solution is diluted with 600 ml. of water. The oily product is taken up in ether, washed with dilute sodium bicarbonate solution and four portions of water and dried over sodium sulfate. Evaporation of the ether in vacuo leaves the title compound as a light yellow viscous oil.

Aufarbeitung

  1. additionThe solution is diluted with 600 ml
  2. washwashed with dilute sodium bicarbonate solution and four portions of water
  3. dry with materialdried over sodium sulfate
  4. customEvaporation of the ether in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-baa1316a04764c80889221a54e97d61f
Quelldatensatz
uspto-grants-1978_01
Patentnummer
US04066675

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