Acetophenone → 1-Phenylethyl Acetate

HRID 1885068

Reaktionsgleichung

Reaktionsgleichung von HRID 1885068
C(C1C=CC=CC=1)C.N([O:11][C:12](C)(C)[CH3:13])=O.ON1C(=O)C2=CC=CC=C2C1=O.C(=NO)(C1C=CC=CC=1)C.[N+](C(C1C=CC=CC=1)C)([O-])=O.[C:49]([C:52]1[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=1)(=[O:51])[CH3:50]>C(O)(=O)C>[C:12]([O:51][CH:49]([CH3:50])[C:52]1[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=1)(=[O:11])[CH3:13]

Komponenten

8

Edukt 6

HCID 7410AcetophenoneHCID 7500EthylbenzeneHCID 10665N-HydroxyphthalimideHCID 10906Tert-Butyl nitriteHCID 236181-NitroethylbenzeneHCID 69185Acetophenonoxime

Produkt 1

HCID 623411-Phenylethyl Acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Reaktionsbedingungen

Temperatur
100 °C

Versuchsvorschrift

Ethylbenzene (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 100° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that acetophenone oxime, (1-nitroethyl)benzene, acetophenone, and α-methylbenzyl acetate were formed in yields of 32%, 5%, 23%, and 15%, respectively.

Aufarbeitung

  1. customThe resulting reaction mixture

Quellen und Nachweise

ORD-Eintrag
ord-cd16011e93fa4954bffa561b237bb692
Quelldatensatz
uspto-grants-2004_07
Patentnummer
US06768023B2

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