Water → HCID 20322157, Verbindung

HRID 2083109Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2083109
Cl[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH2:9][CH2:10][CH2:11][Cl:12].[C:13]([O-:16])(=[O:15])[CH3:14].[Na+].O>C(O)(=O)C>[Cl:12][CH2:11][CH2:10][CH2:9][C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][C:3]=1[CH2:2][O:16][C:13](=[O:15])[CH3:14]

Komponenten

5

Edukt 3

HCID 962WaterHCID 517045Sodium AcetateHCID 123739901-(Chloromethyl)-2-(3-chloropropyl)benzene

Produkt 1

HCID 20322157HCID 20322157, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

70 g (345 mmols) of 3-(2-Chloromethylphenyl)-propyl chloride (JACS 75, 2053 (1953) and 50 g (0.61 mmol) of sodium acetate were heated to the boiling point while stirring in 250 ml of glacial acetic acid. It resulted from the thin layer chromatography that the reaction was finished after 41/2 hours. After cooling about 700 ml of water were added and the product was extracted with benzene. The organic phase was washed with water, dried and distilled off after evaporation of the solvent. Boiling point0.1 : 101° C.

Aufarbeitung

  1. customIt resulted from the thin layer chromatography that the reaction
  2. custom2 hours
  3. additionwere added
  4. extractionthe product was extracted with benzene
  5. washThe organic phase was washed with water
  6. customdried
  7. distillationdistilled off
  8. customafter evaporation of the solvent
  9. custom101° C.

Quellen und Nachweise

ORD-Eintrag
ord-d5c8ab3f4db748b987a1fb2eee24d993
Quelldatensatz
uspto-grants-1978_04
Patentnummer
US04083990

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