Methanol → 2-ethyl-2-adamantyl Methacrylate p-acetoxystyrene

HRID 2120031

Reaktionsgleichung

[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:14]2[CH2:15][CH:10]3[CH2:11][CH:12]([CH2:16][CH:8]1[CH2:9]3)[CH2:13]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20].N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O.CO>C(O)(C)C.CC(C)=O>[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:8]2[CH2:16][CH:12]3[CH2:11][CH:10]([CH2:15][CH:14]1[CH2:13]3)[CH2:9]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20]

Komponenten

Reaktionsbedingungen

Temperatur: 75 °C

Versuchsvorschrift

Into a flask were charged 39.7 g (0.16 mol) of 2-ethyl-2-adamantyl methacrylate, 103.8 g (0.64 mol) of p-acetoxystyrene and 265 g of isopropanol, and the mixture was heated up to 75° C. under a nitrogen atmosphere. Into this solution was dropped a solution prepared by dissolving 11.05 g (0.048 mol) of dimethyl 2,2′-azobis(2-methylpropionate) in 22.11 g of isopropanol. The mixture was aged for about 0.3 hours at 75° C., and for about 12 hours under reflux, then, diluted with acetone. The reaction solution was poured into a large amount of methanol to precipitate a polymer which was filtrated. The amount of the resulted copolymer of 2-ethyl-2-admantyl methacrylate and p-acetoxystyrene was 250 g (weight of wet cake containing methanol).

Aufarbeitung

additionInto this solution was dropped a solution
customprepared
temperaturefor about 12 hours under reflux
customto precipitate a polymer which
filtrationwas filtrated
addition250 g (weight of wet cake containing methanol)

Quellen und Nachweise

ORD-Eintrag: ord-b566d380804248c1b39787bf7b7a0245
Quelldatensatz: uspto-grants-2004_02
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06689531B2

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