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2-Propanol, 1,3-dichloro-, 2-carbamate → Emulphor

HRID 2350835
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 2350835
[C:1]([OH:20])(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[C:21](O)(=[O:39])[CH2:22]CCCCCC/C=C/CCCCCCCC.C(O)(=O)CCCCCCC/C=C\C/C=C\CCCCC.C(O)(=O)CCCCCCC/C=C\C[C@@H](CCCCCC)O.C(Cl)C(OC(N)=O)CCl>O>[CH3:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][O:20][CH2:22][CH2:21][OH:39]
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Komponenten

7

Edukt 5

HCID 685162-Propanol, 1,3-dichloro-, 2-carbamate2×HCID 445639Oleic AcidHCID 637517Elaidic AcidHCID 643684Ricinoleic Acid3×HCID 5280450Linoleic Acid2×

Produkt 1

HCID 5364713Emulphor

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Surface-active dispersing agents in the form of oxyalkylated esters of unsaturated higher fatty acids are preferred. Oxymethylated and/or oxyethylated esters are especially preferred. In this, case, a glyceride type ester is preferred. This ester can be a mono-, di- and tri-glyceride. The oxyalkylated forms of the esters which can be used in accordance with the invention are obtained, in particular, from esters of unsaturated higher fatty acids which can undergo an oxyalkylation, particularly an oxyethylation. Particularly useful fatty acids are oleic acid, elaidic acid, linoleic acid and ricinoleic acid. The oxyethylated glyceride of ricinoleic acid, which can be advantageously used in the form of ethoxylated castor oil is of particular value for the purposes of the present invention. Castor oil consists of 80 to 85% of the glyceride of ricinoleic acid, and in addition the glycerides of oleic (7%), linoleic (3%), palmitic (2%) and stearic (1%) acids. Ethoxylated castor oil is marked by a good solubility in fatty acids, polar solutions and water. The oxyethylated castor oil may be that produced commercially by BASF (trademark: Emulphor EL). This castor oil is a yellow oil, having a freezing point below +20° C., and which is soluble in fatty acids, waxes, castor oil, polar solvents (e.g., trichloroethylene, xylene) and water.

Aufarbeitung

  1. customare obtained

Quellen und Nachweise

ORD-Eintrag
ord-9763bbb531f843ebb14e5a59ad155215
Quelldatensatz
uspto-grants-1989_10
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US04871620

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