Benzothiazole → 1-Methyl-4-Prop-1-En-2-Ylcyclohexene

HRID 2394231Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2394231
S1C2C=CC=CC=2N=C1.[CH3:10][C:11]1[C:16](=[O:17])[CH2:15][CH:14]([C:18]([CH3:20])=[CH2:19])[CH2:13][CH:12]=1.C[CH2:22]/[CH:23]=[CH:24]\[CH2:25][C:26]1[C:30](=O)[CH2:29][CH2:28][C:27]=1[CH3:32].CC1CCC(=O)C=1CC=CCC>>[CH3:10][C:11]1[CH2:16][CH2:15][C@@H:14]([C:18]([CH3:20])=[CH2:19])[CH2:13][CH:12]=1.[CH3:19][C:18]([CH:14]1[CH2:15][CH:16]2[O:17][C:11]2([CH3:10])[CH2:12][CH2:13]1)=[CH2:20].[CH3:22][C:23]1[CH2:29][CH2:30][CH:26]([C:27]([CH3:28])=[CH2:32])[CH2:25][CH:24]=1

Komponenten

7

Edukt 4

HCID 7222BenzothiazoleHCID 7439Carvone, (+-)-HCID 102612-Cyclopenten-1-one, 3-methyl-2-(2Z)-2-pentenyl-HCID 1549018Jasmone

Produkt 3

HCID 223111-Methyl-4-Prop-1-En-2-YlcyclohexeneHCID 91496Limonene oxideHCID 440917(+)-Limonene

Versuchsvorschrift

Benzothiazole, an aromatic sulfonazole, was obtained from Sigma-Aldrich in a 96% formulation, catalog No.1-133-8. Carvone, a 6-carbon ring terpene with ketone on the ring, in particular, (2-methyl-5-(1-methylethyenyl)- 2-cylco-hexene-1 -one, was obtained from Sigma-Aldrich in a 98% formulation, catalog No. 12393-1. Cis-jasmone, a terpene with the chemical name 3- methyl-2-(2-pentenyl)-2-cylco-penten-1-one, was obtained from Sigma-Aldrich in a 90% formulation, catalog No. 277444. Limonene, a terpene, was obtained in a 97% mixture of cis and trans forms of limonene oxide, chemica name 1-methyl-4-(1-methylethenyl) cylcohexene, from Sigma-Aldrich, catalog No. 21832-4. Cinieole, a terpene with the chemical name 1,3,3-trimethyl-2- oxabicyclo-(2.2.2)octane, was obtained from Sigma-Aldrich in a 99% formulation, catalog No. C8060-1. Trans-cinnamaldehye, an aromatic aldehyde with the chemical name 3-phyl-2-propenal was obtained from Sigma-Aldrich in a 99+% formulation, catalog No. 23996-8.

Quellen und Nachweise

ORD-Eintrag
ord-1f38dd9d599840899663f633079039b5
Quelldatensatz
uspto-grants-1998_09
Patentnummer
US05811372

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