Cyclohexanone → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 256788

Reaktionsgleichung

Reaktionsgleichung von HRID 256788
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][N:2]=1.C1(=O)CCCCC1>CN1CCCC1=O.[Cu]I>[CH2:9]=[CH:10][C:1]#[N:2].[CH2:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

Komponenten

5

Edukt 2

HCID 7967CyclohexanoneHCID 8405Isoquinoline

Produkt 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)Ausbeute 10 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)KatalysatorHCID 13387N-methyl-2-pyrrolidoneLösungsmittel

Versuchsvorschrift

A solution of 2.0 g. CuI, 1.4 g. isoquinoline (1:1 ratio), 50.0 g. N-methylpyrrolidone solvent, 46.6 g. cyclohexanone and 0.20 g. Lustran SAN 31-1,000 (10% on CuI) was prepared. The resulting coating solution was coated on 7 mil raw PET with number 10 Meyer rod and dried three minutes at 240° F. The coating had very good uniformity and clarity and was gold and blue iridescent and lustrous. The resistivity measured 13-20×107 Ω/sq. The solution after time showed some precipitation, which crystals were redissolved upon reheating.

Aufarbeitung

  1. customdried three minutes at 240° F
  2. customsome precipitation, which crystals
  3. dissolutionwere redissolved

Quellen und Nachweise

ORD-Eintrag
ord-3110b0bfc3814e4280160de68cfb5d7b
Quelldatensatz
uspto-grants-1993_11
Patentnummer
US05259992

Verknüpfte Notizen

Wird geladen…