N,N-Dimethylbenzylamine → HCID 21425139, Verbindung

HRID 258955

Reaktionsgleichung

Reaktionsgleichung von HRID 258955
[Br:1][CH:2]([Si:4]([O:11][CH2:12][CH3:13])([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7])[CH3:3].C([Si](Cl)(Cl)Cl)CCCC.[CH2:23]([N:30]([CH3:32])[CH3:31])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>CC(=O)CC>[Br-:1].[CH2:23]([N+:30]([CH3:32])([CH3:31])[CH:2]([Si:4]([O:11][CH2:12][CH3:13])([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7])[CH3:3])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1

Komponenten

5

Edukt 3

HCID 7681N,N-DimethylbenzylamineHCID 7885TrichloropentylsilaneHCID 21425138alpha-Bromoethyltriethoxysilane

Produkt 1

HCID 21425139HCID 21425139, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6569Methyl Ethyl KetoneLösungsmittel

Versuchsvorschrift

In a manner like that used for the preparation of alpha-bromoethyltriethoxysilane, alpha-bromoamyltriethoxysilane is prepared in two steps from amyltrichlorosilane (commercially available). One-quarter mole of alpha-bromoamyltriethoxysilane (78.5g) is refluxed for 12 hours with 0.25 moles (33.75g) of benzyldimethylamine in 125 ml. of 2-butanone. The product, alpha-(benzyldimethylammonio)ethyltriethoxysilane bromide is isolated by removing the solvent under vacuum.

Quellen und Nachweise

ORD-Eintrag
ord-c4e838e1b7d3491287275096ae3d8e91
Quelldatensatz
uspto-grants-1977_07
Patentnummer
US04035411

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