Acetic Acid → HCID 21317597, Verbindung

HRID 263002Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 263002
Cl[CH2:2][CH2:3][S:4][CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26]C(=O)C)[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14]CC)=[O:13].OO.[OH2:32].C(O)(=[O:35])C>CCOCC>[CH:3]([S:4]([CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([OH:26])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])(=[O:35])=[O:32])=[CH2:2]

Komponenten

6

Edukt 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 962WaterHCID 21317532Ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate

Produkt 1

HCID 21317597HCID 21317597, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

A solution of ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate (45.1 g., 0.1 mole) and 30% aqueous hydrogen peroxide (50 ml.) in acetic acid (225 ml.) is allowed to stand 20 hours at 25° C. The solution is diluted with 600 ml. of water. The oily product is taken up in ether, washed with dilute sodium bicarbonate solution and four portions of water and dried over sodium sulfate. Evaporation of the ether in vacuo leaves the title compound as a light yellow viscous oil.

Aufarbeitung

  1. additionThe solution is diluted with 600 ml
  2. washwashed with dilute sodium bicarbonate solution and four portions of water
  3. dry with materialdried over sodium sulfate
  4. customEvaporation of the ether in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-d9a92703651b41ab9b19593138d127a2
Quelldatensatz
uspto-grants-1979_05
Patentnummer
US04155908

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