1-Octene → Gamma-Decalactone

HRID 46746

Reaktionsgleichung

Reaktionsgleichung von HRID 46746
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Komponenten

4

Versuchsvorschrift

Octene-1 in an amount of 2.2 g. and 23.6 g. of ceric ammonium nitrate, Ce(NH4)2 (NO3)6, were refluxed under nitrogen in 200 ml. glacial acetic acid containing 60 g. potassium acetate for less than 0.5 hour, there being obtained a 48% yield of gamma-n-hexyl-butyrolactone.

Quellen und Nachweise

ORD-Eintrag
ord-2c03d4a37bfe48c9975a949c07039ab8
Quelldatensatz
uspto-grants-1979_11
Patentnummer
US04175089

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