Isoprene → Isoprene butadiene

HRID 513970

Reaktionsgleichung

Reaktionsgleichung von HRID 513970
[CH2:1]=[CH:2][C:3](=[CH2:5])[CH3:4].[CH2:6]=[CH:7][CH:8]=[CH2:9].C=CC1C=CC=CC=1>CO>[CH2:1]=[CH:2][C:3](=[CH2:4])[CH3:5].[CH2:6]=[CH:7][CH:8]=[CH2:9]

Komponenten

5

Edukt 3

HCID 6557IsopreneHCID 7501StyreneHCID 78451,3-Butadiene

Produkt 1

HCID 168288Isoprene butadiene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Reaktionsbedingungen

Temperatur
50 °C

Versuchsvorschrift

Into a dried pressure vessel purged with nitrogen, 80 L of cyclohexane solvent and 0.17 L of sec-butyllithium initiator (10% by mass solution in cyclohexane) were charged. After raising the temperature to 50° C., 3.9 L of styrene was added to allow the polymerization to proceed for 3 h. Then, the polymerization was allowed to proceed for 4 h after adding a mixed liquid of 12.1 L of isoprene and 10.9 L of butadiene and further for 3 h after adding 3.9 L of styrene. The resultant reaction liquid was poured into 80 L of methanol, and the precipitated solid matter was separated by filtration and dried at 50° C. for 20 h, to obtain a polystyrene block-poly(isoprene/butadiene) block-polystyrene block, triblock copolymer.

Aufarbeitung

  1. customInto a dried pressure vessel purged with nitrogen, 80 L of cyclohexane solvent and 0.17 L of sec-butyllithium initiator (10% by mass solution in cyclohexane)
  2. additionwere charged
  3. addition3.9 L of styrene was added
  4. customthe polymerization
  5. waitto proceed for 4 h
  6. customThe resultant reaction liquid
  7. customthe precipitated solid matter was separated by filtration
  8. customdried at 50° C. for 20 h

Quellen und Nachweise

ORD-Eintrag
ord-1d887dd659494004bc27ecf4f7ff803a
Quelldatensatz
uspto-grants-2015_08
Patentnummer
US09102849B2

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