Aniline → N-Cyclohexylaniline

HRID 53409

Reaktionsgleichung

Reaktionsgleichung von HRID 53409
C1(=O)CCCCC1.NC1C=CC=CC=1.[N+](C1C=CC=CC=1)([O-])=O.[C:24]1([NH:30][C:31]2[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=2)[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.C1(N(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1>>[CH:31]1([NH:30][C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[CH2:36][CH2:35][CH2:34][CH2:33][CH2:32]1

Komponenten

6

Edukt 5

HCID 6115AnilineHCID 7416NitrobenzeneHCID 7967CyclohexanoneHCID 11487DiphenylamineHCID 11775Triphenylamine

Produkt 1

HCID 74567N-CyclohexylanilineAusbeute 2,9 %

Versuchsvorschrift

Reaction was carried out by the same procedure as in Example I1 except that 32.39 g (0.39 mol) of cyclohexanone, 9.31 g (0.1 mol) of aniline and 24.62 g (0.2 mol) nitrobenzene were used. As a result, the yield of diphenylamine was 89.5%, and 1.8% of triphenylamine and 2.9% of N-cyclohexylaniline were produced.

Aufarbeitung

  1. customReaction

Quellen und Nachweise

ORD-Eintrag
ord-6a4a9d71f6204543b7bc12d011dc8c18
Quelldatensatz
uspto-grants-1997_04
Patentnummer
US05618980

Verknüpfte Notizen

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